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Beilstein J. Org. Chem. 2013, 9, 1472–1479, doi:10.3762/bjoc.9.167
Graphical Abstract
Scheme 1: Oxidative conversion of 1,3-dicarbonyl compounds to carboxylic acids with CAN.
Figure 1: Energy diagram for the unsubstituted arene with the carbonyl groups anti to each other. For TS1a’ t...
Figure 2: Possible products from the ortho cyclization of 1g and 1j.
Scheme 2: Proposed mechanism for the conversion of δ-aryl-β-dicarbonyl compounds to β-tetralones (path A) and...